Gallagher recently released our High Performance Elastomer Seals for the Instrumentation Industry White Paper. This was written by Russ Schnell, an Elastomer Consultant contracted by Gallagher Fluid Seals, and a former Senior Application Engineer with the Kalrez® perfluoroelastomer parts business at DuPont. This white paper is now available for download on our Resources page.
Below is the second section of the white paper, diving into applications where the measurement is made in analytical laboratories which employ numerous solvents in a wide range of analyses and test equipment.
The final set of instrumentation is laboratory test equipment. As opposed to the laboratories in chemical plants, which often perform the same routine analyses on plant process streams, general analytical labs employ numerous solvents in a wide range of analyses and test equipment. As such, the ability of seals to resist a breadth of chemicals without degradation or leaching contaminants into a sample is of great importance. Although instrument seals are easily replaced in a laboratory environment, this operation still takes a technician time. It is always easier if the system can be flushed with a cleaning solvent and then be ready to run the next sample versus having to change out an elastomer seal due to incompatibility with a solvent.
FFKMs, also known as perfluoroelastomers, were first developed in the 1960s for applications involving high temperatures and/or aggressive chemicals. Perfluoroelastomers exhibit many properties similar to PTFE (polytetrafluoroethlyene, or Teflon®), and are considered inert in almost all solvents. However, PTFE is a plastic, and when compressed, it will not recover to its original shape. On the other hand, elastomers contain crosslinks, which act as springs to give the material resiliency and the ability to recover after a part has been compressed - this resistance to permanent compression gives the material the ability to maintain a seal over time. (To learn more about perfluoroelastomers, download our Introduction to Perfluoroelastomers White Paper).
The article below was recently published on FlowControlNetwork.com, and discusses how FFKMs are being used in oil & gas exploration, as production companies are increasingly operating in high-pressure, high-temperature (HPHT) downhole conditions.
Improving technologies and methods to increase the recovery of oil from existing reservoirs is a global challenge. In the U.S., oil production at reservoirs can include three phases: primary, secondary and tertiary (or enhanced) recovery. The U.S. Department of Energy (DOE) estimates that primary recovery methods — which rely on the natural pressure of the reservoir or gravity to drive oil into the wellbore, combined with pumps to bring the oil to the surface — typically tap only 10 percent of a reservoir’s oil. Furthermore, secondary efforts to extend a field’s productive life — generally by injecting water or gas to displace oil and drive it to a production wellbore — still only push recovery totals to between 20 and 40 percent of the original oil in place. Clearly, much untapped oil and gas remains in existing wells.
Gallagher recently released our High Performance Elastomer Seals for the Instrumentation Industry White Paper. This was written by Russ Schnell, an Elastomer Consultant contracted by Gallagher Fluid Seals, and a former Senior Application Engineer with the Kalrez® perfluoroelastomer parts business at DuPont. This white paper is now available for download on our Resources page.
Below is the first section of the white paper, diving into applications where the measurement is made at the process and the results then transmitted to a control system. This section will review the four types of in-line measurement devices, all involving slightly different elastomer sealing applications.
Flowmeters are used to measure the flow of liquid. In this section we will only consider the measurement of liquid flow in a closed piping system. Several examples of flow measurement devices include: flowmeters, Venturi tubes and orifice plates.
Note that these devices are “in-line” and require isolating the process line to remove and repair, or replace the measurement device. Shutting down a process to remove a device is time consuming, involves loss of production, and may require specific procedures to protect the operators and environment when a line is opened. All of these devices require seals to prevent leakage of the process to the environment and the elastomer seals should last the life of the flowmeter. For aggressive chemicals or high temperature applications, FKM or FFKM seals are an excellent choice. These products offer a long service life and resist deterioration in harsh environments.
Gallagher recently released our High Performance Elastomer Seals for the Instrumentation Industry White Paper, available for download on our site. This was written by Russ Schnell, an Elastomer Consultant contracted by Gallagher Fluid Seals, and a former Senior Application Engineer with the Kalrez® perfluoroelastomer parts business at DuPont. This white paper is now available for download on our Resources page.
The term instrumentation covers a wide variety of applications. In the broadest sense, instrumentation may be considered as any equipment used for measurements. This equipment may be in a process stream and include devices such as flowmeters, pressure gages, and inline probes. Data from these devices are used for process control. In automobiles, sensors are used for a variety of applications including measuring the exhaust stream to “tune” the engine to yield maximum performance. Analytical laboratory instruments such as chromatographs and flame ionization detectors are used to determine the composition of samples. Instruments are used in the medical industry for product analysis as well as analysis of blood and urine samples. Of course this is only a partial list of the many applications involving instruments.
Gallagher Fluid Seals recently made our Fluoroelastomer Basics webinar available on the website.
This webinar will discuss:
An elastomer is made up of long chain polymers which are connected by crosslinks. Crosslinks are analogous to springs and provide an "elastic" (recovery) nature to the material. The crosslinks are relatively stable, but can break down under extreme temperatures and pressures.
Gallagher Fluid Seals recently added a new white paper to its Resources Page, Perfluoroelastomers for the Semiconductor Industry, written by Russ Schnell. Below is an excerpt from the new white paper discussing the key reasons to choose perfluoroelastomers over fluoroelastomers for semiconductor manufacturing. You can download the white paper in its entirety by clicking on the thumbnail to the right.
Perfluoroelastomers (e.g. Kalrez® parts), often replace fluoroelastomer (e.g. Viton®) in semiconductor applications. However, even though perfluoroelastomers are the highest performance elastomers, there are still subtle differences between products. It is suggested that the elastomer supplier be contacted regarding the optimum product and seal design for specific applications. As mentioned above the key characteristics of perfluoroelastomers include:
Gallagher Fluid Seals recently added a new white paper to its Resources Page, Perfluoroelastomers for the Semiconductor Industry, written by Russ Schnell. Below is an excerpt from the new white paper discussing plasma process manufacturing. You can download the white paper in its entirety by clicking on the thumbnail to the right.
Although this is a smaller segment of the semiconductor chip manufacturing industry, it still plays an important role. Wet processes can be used in cleaning, etching, and other steps in chip manufacture. Wafers may be cleaned and rinsed after initial wafer preparation. This step removes residual particles and other contamination on the wafer surface. The wafer may then be exposed to chemicals for adhesion promotion and/or photoresist deposition. After photoresist is applied to the wafer surface, the wafer can be exposed to a number of photolithography steps. The wafer may then be exposed to liquid developer solutions and photoresist stripping solutions. Resist strippers usually involve aggressive acids or organic solvents. Finally, wet processes can also be used in etching processes, which typically involve strong acids.
Gallagher Fluid Seals recently added a new white paper to its Resources Page, Perfluoroelastomers for the Semiconductor Industry, written by Russ Schnell. Below is an excerpt from the new white paper discussing thermal process manufacturing. You can download the white paper in its entirety by clicking on the thumbnail to the right.
The term “thermal process” covers a fairly wide range of applications. Per the name, these application temperatures are generally higher than plasma processes, ranging up to 300°C. This general term can cover processes including: Sub Atmospheric Chemical Vapor Deposition (SACVD), Metal CVD, Low Pressure CVD (LPCVD), Rapid Thermal Processing (RTP), and Oxidation or Diffusion furnaces. In these applications the wafers and the equipment that surrounds them, are heated to extremely high temperatures. In the case of thermal deposition, the high temperatures aid in the uniformity of the coating thickness.
Rapid Thermal Processing is used to very rapidly heat a wafer up to temperatures of 1000°C or greater for short periods of time. “Rapid Thermal Processing (RTP) can be used to reduce the thermal redistribution of impurities at high temperature…. RTP was originally developed for ion implant anneal, but has broadened its application to oxide growth, chemical vapor deposition, and silicidation.” For oxidation or diffusion furnaces, the applications are different, but still involve high temperatures. For oxidation applications, the procedure involves formation of a thin oxide film on the wafer surface. For diffusion applications, the furnace may assist in silicon dioxide formation on the wafer surface or it may be used to diffuse dopants in the wafer. For these applications, temperatures may range up to 1200°C.
Gallagher Fluid Seals recently added a new white paper to its Resources Page, Perfluoroelastomers for the Semiconductor Industry, written by Russ Schnell. Below is an excerpt from the new white paper discussing plasma process manufacturing. You can download the white paper in its entirety by clicking on the thumbnail to the right.
In plasma process manufacturing, a remote plasma source generates a plasma gas. Note that this type of process is run in a vacuum environment. This gas is composed of ions, electrons, radicals and neutral particles. The flow of these particles must be carefully controlled for etching, deposition, or ashing/stripping processes. These processes often use oxygen, fluorine, and other exotic plasma gases, which are extremely aggressive to many materials. In addition, cleaning processes often use oxygen plasma. Precise control of the plasma gas in the chamber is critical so processes perform as expected, for all the individual chips, across the entire diameter of the wafer.
In the plasma process, which typically operate under a high vacuum, FFKM seals can be critical for maintaining system integrity and providing a long seal life. The term “long seal life” is relative. However these seals must perform at high temperatures, up to 250°C, and still maintain low offgassing and low particle generation to prevent contaminating the manufacturing process. In some cases, under extremely aggressive conditions of plasma gases and high temperatures, 6-8 weeks may be considered a long service life for an elastomer seal.
Gallagher Fluid Seals recently added a new white paper to its Resources Page, Perfluoroelastomers for the Semiconductor Industry, written by Russ Schnell. Below is an excerpt from the new white paper. You can download it in its entirety by clicking on the thumbnail to the right.
The following is a simplified process chart for chip manufacture in the semiconductor industry:
Following the process shown above: