Polytetrafluoroethylene (PTFE) is commonly known as a coating for pans under the DuPont trade name Teflon™. It is also superbly suited as a sealant and is superior to many materials in specific ways. For example, it can be used at low and high temperatures and in combination with gasoline, solvents, water and other polar media such as lyes, standard lubricants and brake fluid. PTFE’s chemical resistance is nearly universal.
In 1938, while working for DuPont, American chemist Roy Plunkett was looking for a substitute for the fluorohydrocarbon Freon, which his employer was only allowed to sell to General Motors’ Frigidaire division for patent-related reasons. For his research, he had obtained a supply of tetrafluoroethylene (TFE), which was used as refrigerator coolant. He stored it in small pressurized gas cylinders at low temperatures. When he was ready to use the gas after a fairly long storage period, none was left in the container. But its weight was unchanged. After it was opened, there were white crumbs inside and the inner walls of the container were covered with a thin layer. Plunkett quickly realized that the TFE gas had been polymerized into a plastic. This new plastic, PTFE, proved to be completely resistant to chemical exposure. Not even aqua regia¹ could harm it in any way. But its production was so costly that practical uses seemed inconceivable.