Perfluoroelastomers
- July 24, 2018
FFKMs, also known as perfluoroelastomers, were first developed in the 1960s for applications involving high temperatures and/or aggressive chemicals. Perfluoroelastomers exhibit many properties similar to PTFE (polytetrafluoroethlyene, or Teflon®), and are considered inert in almost all solvents. However, PTFE is a plastic, and when compressed, it will not recover to its original shape. On the other hand, elastomers contain crosslinks, which act as springs to give the material resiliency and the ability to recover after a part has been compressed - this resistance to permanent compression gives the material the ability to maintain a seal over time. (To learn more about perfluoroelastomers, download our Introduction to Perfluoroelastomers White Paper).
The article below was recently published on FlowControlNetwork.com, and discusses how FFKMs are being used in oil & gas exploration, as production companies are increasingly operating in high-pressure, high-temperature (HPHT) downhole conditions.
HOW FFKMS PROTECT COMPONENTS IN ENHANCED OIL RECOVERY OPERATIONS
Companies are increasingly operating in high-pressure, high-temperature downhole conditions.
Improving technologies and methods to increase the recovery of oil from existing reservoirs is a global challenge. In the U.S., oil production at reservoirs can include three phases: primary, secondary and tertiary (or enhanced) recovery. The U.S. Department of Energy (DOE) estimates that primary recovery methods — which rely on the natural pressure of the reservoir or gravity to drive oil into the wellbore, combined with pumps to bring the oil to the surface — typically tap only 10 percent of a reservoir’s oil. Furthermore, secondary efforts to extend a field’s productive life — generally by injecting water or gas to displace oil and drive it to a production wellbore — still only push recovery totals to between 20 and 40 percent of the original oil in place. Clearly, much untapped oil and gas remains in existing wells.
- July 10, 2018
Gallagher recently released our High Performance Elastomer Seals for the Instrumentation Industry White Paper. This was written by Russ Schnell, an Elastomer Consultant contracted by Gallagher Fluid Seals, and a former Senior Application Engineer with the Kalrez® perfluoroelastomer parts business at DuPont. This white paper is now available for download on our Resources page.
Below is the first section of the white paper, diving into applications where the measurement is made at the process and the results then transmitted to a control system. This section will review the four types of in-line measurement devices, all involving slightly different elastomer sealing applications.
In-Line Process Applications
Flowmeters
Flowmeters are used to measure the flow of liquid. In this section we will only consider the measurement of liquid flow in a closed piping system. Several examples of flow measurement devices include: flowmeters, Venturi tubes and orifice plates.
Note that these devices are “in-line” and require isolating the process line to remove and repair, or replace the measurement device. Shutting down a process to remove a device is time consuming, involves loss of production, and may require specific procedures to protect the operators and environment when a line is opened. All of these devices require seals to prevent leakage of the process to the environment and the elastomer seals should last the life of the flowmeter. For aggressive chemicals or high temperature applications, FKM or FFKM seals are an excellent choice. These products offer a long service life and resist deterioration in harsh environments.
- April 03, 2018
Gallagher recently published its Failure Modes of Elastomers in the Semiconductor Industry White Paper, now available for download on our site. This white paper discusses common issues that occur with elastomer seals in the semiconductor industry. The excerpt below is the fourth and final section of our new white paper, discussing Volatiles (offgassing) and Particle Generation. To download the white paper in its entirety, visit our Resources Page, or click on the image to the right.
Failure Modes of Elastomers in the Semiconductor Industry
High performance elastomers are found in many applications in the semiconductor industry (see paper titled Perfluoroelastomers in the Semiconductor Industry). Though perfluoroelastomer (FFKM) seals are formulated to meet the highest performance requirements of integrated circuit (chip) manufacturers, even these elastomers can’t solve every sealing application nor will they last forever in service. Additionally, end users need to understand subtle performance differences between perfluoroelastomers in the same product line. For example, one product may be better at minimizing particle generation while another may be better for high temperature services.
- March 13, 2018
Gallagher recently published its Failure Modes of Elastomers in the Semiconductor Industry White Paper, now available for download on our site. This white paper discusses common issues that occur with elastomer seals in the semiconductor industry. The excerpt below is the third section of our new white paper, discussing O-Ring Stretch, Chemical Attack, Plasma Cracking, and Permeation. To download the entire white paper, visit our Resources Page, or click on the image to the right.
Failure Modes of Elastomers in the Semiconductor Industry
High performance elastomers are found in many applications in the semiconductor industry (see paper titled Perfluoroelastomers in the Semiconductor Industry). Though perfluoroelastomer (FFKM) seals are formulated to meet the highest performance requirements of integrated circuit (chip) manufacturers, even these elastomers can’t solve every sealing application nor will they last forever in service. Additionally, end users need to understand subtle performance differences between perfluoroelastomers in the same product line. For example, one product may be better at minimizing particle generation while another may be better for high temperature services.
- February 15, 2018
Gallagher recently published its Failure Modes for Elastomers in the Semiconductor Industry White Paper, now available for download on our site. This white paper discusses common issues that occur with elastomer seals in the semiconductor industry. The excerpt below is the second section of our new white paper, discussing Loss of Sealing Force, and Extrusion. To download the white paper in its entirety, visit our Resources Page, or click on the image to the right.
Failure Modes of Elastomers in the Semiconductor Industry
High performance elastomers are found in many applications in the semiconductor industry (see paper titled Perfluoroelastomers in the Semiconductor Industry). Though perfluoroelastomer (FFKM) seals are formulated to meet the highest performance requirements of integrated circuit (chip) manufacturers, even these elastomers can’t solve every sealing application nor will they last forever in service. Additionally, end users need to understand subtle performance differences between perfluoroelastomers in the same product line. For example, one product may be better at minimizing particle generation while another may be better for high temperature services.
- February 06, 2018
Gallagher recently published its Failure Modes of Elastomers in the Semiconductor Industry White Paper, now available for download on our site. This white paper discusses common issues that occur with elastomer seals in the semiconductor industry. The excerpt below is the first section of our new white paper, discussing groove design and seal leakage. To download the entire white paper, visit our Resources Page, or click on the image to the right.
Failure Modes for Elastomers in the Semiconductor Industry
High performance elastomers are found in many applications in the semiconductor industry (see paper titled Perfluoroelastomers in the Semiconductor Industry). Though perfluoroelastomer (FFKM) seals are formulated to meet the highest performance requirements of integrated circuit (chip) manufacturers, even these elastomers can’t solve every sealing application nor will they last forever in service. Additionally, end users need to understand subtle performance differences between perfluoroelastomers in the same product line. For example, one product may be better at minimizing particle generation while another may be better for high temperature services.
- November 28, 2017
NEW White Paper Available!
Gallagher Fluid Seals recently added a new white paper to its Resources Page, Perfluoroelastomers for the Semiconductor Industry, written by Russ Schnell. Below is an excerpt from the new white paper discussing the key reasons to choose perfluoroelastomers over fluoroelastomers for semiconductor manufacturing. You can download the white paper in its entirety by clicking on the thumbnail to the right.
Perfluoroelastomers (e.g. Kalrez® parts), often replace fluoroelastomer (e.g. Viton®) in semiconductor applications. However, even though perfluoroelastomers are the highest performance elastomers, there are still subtle differences between products. It is suggested that the elastomer supplier be contacted regarding the optimum product and seal design for specific applications. As mentioned above the key characteristics of perfluoroelastomers include:
- Lower offgassing than other elastomers, especially at temperatures above 200°C, which lowers the risk of product contamination.
- Better sealing force retention (lower compression set) at temperatures over 200°C, which is critical for longer service.
Best overall chemical resistance of any elastomer family. - Formulations with extremely low particle generation in aggressive process environments.
- Generally higher gas permeation than fluoroelastomers.
- Higher coefficient of thermal expansion when compared to fluoroelastomers. Proper seal design will account for this and optimize performance.
- September 12, 2017
NEW White Paper Available!
Gallagher Fluid Seals has added a new white paper to its Resources Page, Perfluoroelastomers for the Semiconductor Industry, written by Russ Schnell. Below is an excerpt from the new white paper. You can download it in its entirety by clicking on the thumbnail to the right.
The semiconductor industry, one of today’s major industries, produces integrated circuits (chips) which have found their way into everyday devices from toasters to smartphones to high speed computers. Integrated circuits are expected to perform operations faster and faster while attaining ever higher levels of reliability. As these chips become more complex and powerful the process for their manufacture becomes more complicated. Years ago a chip may have gone through 100 steps as underlying circuits were constructed. Now chips may go through more than 400 steps and the complexity of these circuits, and their capability, has greatly increased. This also results in more opportunities for problems during manufacture. Line widths, the width of the electrical pathways, have decreased in order to pack more capacity into each chip. This dictates that contaminants from the production equipment, gas streams, seals, etc., must be essentially eliminated to avoid contamination and chip malfunction.
- August 22, 2017
Article re-posted with permission from Parker Hannifin Sealing & Shielding Team.
Original content can be found on Parker’s Blog.
Solving Long Time Industry Problem
For several years, one of the biggest drawbacks of “chemically resistant” FFKMs, or perfluoroelastomers, has been their relatively poor compression set resistance. Typically, compounding these materials to be extremely resistant to many different chemical environments comes with the drawback of having to give up their ability to resist taking a set after being under high temperatures for an extended period. Parker's solution to this industry challenge is ULTRA FF156.
Best in class compression set resistance
Compression set refers to a common failure mode of elastomers where a seal permanently flattens out while in application and the joint begins to leak. A material's resistance to this permanent deformation can be easily tested in the lab. To do so, a seal’s thickness is measured, then that seal is compressed about 25% before being heated in an oven at a particular temperature for a predetermined amount of time. That seal is then removed from the oven and the thickness is remeasured.
- April 25, 2017
Gallagher recently released our Introduction to Perfluoroelastomers White Paper, available for download on our site. This was written by Russell Schnell, a current contracted employee of Gallagher Fluid Seals, and more importantly, a former Senior Application Engineer with the Kalrez® perfluoroelastomer parts business at DuPont. The following is the third and final excerpt from the White Paper, discussing seal design and a cost-benefit analysis of using perfluoroelastomer seals.
Seal Design with Perfluoroelastomer Seals
Care must be taken when designing and using seals made of perfluoroelastomers. These elastomers typically have a higher coefficient of thermal expansion when compared to other elastomers; plus, they are often used at higher temperatures. If the seal gland design is not correct, seal extrusion will occur, resulting in seal failure. For example, a fluoroelastomer seal is scheduled for replacement with a perfluoroelastomer seal, due to high application temperatures. Shortly after this substitution, the FFKM seal fails due to extrusion. The probable cause is that the seal gland volume was too small to accommodate the thermal expansion of the high performance perfluoroelastomers, a factor that many of today’s seal design handbooks do not adequately take into account.